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研究CMC、溶质溶剂和溶质溶质交互的铜(II)肥皂来自食用油在苯甲醇系统在303 K

作者(年代):米纳克希Saxena Rashmi沙玛,Renu Bhutra, Pragya坦克和m·r·k·Sherwani

分析了铜皂准备从各种食用油的胶束在非水介质特性不同的极性。目前的工作处理的研究铜(II)芥末(CM)和大豆(方案)soap在20%和40%甲醇-苯系统。密度肥皂各种浓度的解决方案已经被使用密度数据,测量和摩尔体积和表观摩尔体积计算以确定临界胶束浓度(cmc)在不同的溶剂成分、性质和胶束形成的大小和测试的有效性马森方程,它提供了一个合理的解释为溶质-溶剂和溶质-溶质与溶剂的极性变化的交互。cmc值被发现在更高更大的体积百分比比更高的体积百分比的苯甲醇。It has been observed that apparent molar volume decreases with the increase in the polar content in the solvent mixture for both the soaps v (20%) > v (40%). The apparent molar volume for CM soap is found to be higher than that of CSo soap for both the solvent compositions. Further, it has been observed that as the number of ionic polar heads increases in the soap content, the solute – solvent interaction also increases in both solvent mixtures i.e. 0v2 (CSo) > 0v2 (CM)